Beilstein J. Org. Chem.2023,19, 1755–1765, doi:10.3762/bjoc.19.128
; columnarliquidcrystal; organic electronics; perylene; pyrene; Introduction
Conjugated organic molecules have been widely investigated due to their interesting transport properties and promising applications as active layer in organic photovoltaics (OPVs), organic field effect transistors (OFETs
the charge carrier mobility (parallel vs perpendicular to the columnar axis) of up to ten orders of magnitude [3][4][5][6][7]. In 1994, Adam and collaborators obtained a hole-mobility of up to 0.1 cm2 V−1 s−1 for a triphenylene-based columnarliquidcrystal [8], motivating intense research activity to
from strong π–π interactions [7][21][22][23][24].
In this work, we investigated a perylene and a pyrene-based columnarliquidcrystal in hole-only and electron-only devices to compare their charge carriying properties. The molecular organization and photophysical performances are coherent with the
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Graphical Abstract
Scheme 1:
Molecular structures of compounds 1 and 2.
Beilstein J. Org. Chem.2011,7, 198–203, doi:10.3762/bjoc.7.26
experiments. Amphiphilic dendritic peptides G3 show good organogel properties with a minimum gelation concentration as low as 1 wt %. Furthermore, amphiphilic dendritic peptides G3 can form a hexagonal columnarliquidcrystal assembly over a wide temperature range.
Keywords: amphiphilic; dendritic peptides
characteristic of hexagonal columnar liquid crystals. The conic fan-shaped textures of G3 grow (Figure 6B), and no longer change at 50 °C (Figure 6C). Figure 7 shows the XRD scan for the birefringent phase of G3 at 50 °C. The birefringent phases of G3 were further confirmed as a hexagonal columnarliquidcrystal